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EFFECT OF WATER SOLUBLE FERTILIZERS ON IMPROVEMENT OF CALCAREOUS AND ALKALINE SOILS
MR.R.R.SHAH AND MR. J.K.SHARMA VARDHAMAN HI-TECH AGRO PRODUCTS, PUNE
 About 11 Million Hectares of cultivable soils in India are alkaline or saline (including coastal saline) in nature. The productivity of crops grown in alkaline soils is low, basically because the pH of these soils ranges above 8.0 to 10.0. The suitable pH for most crops to yield high produce is between 6.5 to 7.5. Very few crops can grow in Acidic (Coastal Sandy Acidic) or Alkaline soil (pH more than 8.5), while most acidic soils can be improved by comparatively easily process of liming, improving the alkaline or calcareous soils is difficult and long duration process. Tlie nature of the soil vis-a-vis alkalinity or acidity is important because the uptake of nutrients by the plant roots is strongly influenced by soil pH. This is especially true for vital micronutrients. As the pH increases in alkaline soils, the availability of Nitrogen, Phosphates, Iron, Manganese, Copper, Zinc and Boron decreases. Absorption eventually is blocked completely, even when there is generous supply in soil. If the acidity increases beyond pH 5.0, very less of the nutrients except Iron and Manganese can be absorbed by the plant roots. The phenomenon is due to leaching of Nitrates and fixation of nutrient Ions in the soil matrix. All nutrients are taken up by roots and plants in Ionic form as water solution, In the conventional method of agriculture and fertilization the plants depend for their nutrition and growth on nutrients present in the soil and applied through fertilizers.
Due to alkaline and saline nature of the soil many nutrient elements are lost due to leaching and fixation and are not absorbed by the plants. Annexure -1, below gives suitable pH for good take up of nutrients by the plants.

ANNEXURE NO.1, SUITABLE pH FOR PLANT NUTRIENT TAKE UP :-

Nutrient Best pH Range
Nitrates 6.0-7.0
Potassium 6.0-7.0
Calcium 7.5-8.0 ,
Phosphates 6.0-7.0
Magnesium 5.5-7.5
Sulphur 5.5-7.5
Iron 4.0-6.5
Manganese 5.0-6.5
Zinc 5.0-6.5
Copper 5.0-6.5
Boron 5.0 - 7.5
Molybdenum 6.5-9.0
Annexure No. 2 gives an indication of suitable pH for uptake of nutrient by plants.

In areas with considerable rains, land under crop production gradually acidifies. In arid areas, regular irrigation combined with improper drainage results in salt accumulation and raises pH. In both cases availability of nutrients to plants worsens.
In alkaline and saline soil problem of fixation of nutrient ions with the clay particles is common. Application of Gypsum (Phospho) replaced Sodium levels with Calcium. Thus releasing sulphate ion which in contact with moisture generates acid and reduced pH of the soil. However,this may increase salinity of subsoil, water due to leaching of sodium salts, or may increase E.C. of soils. The process has also long term effectivity.
The effective solution to the problem is drip irrigation, Mini Sprinkler Irrigation and Foliar Spray of dilute water solution of water soluble acidic fertilizers. In this system of Fertigation (Irrigation + Fertilization), the nature of soil plays a minor role where it acts only as growing base for plants. Complex water soluble fertilizers consist of all required nutrients (except Calcium) and are acidic in nature, yielding acidic water solution (pH 5.5 - 6.5). e.g. Grade NPK 19;19;19, Fully water soluble complex fertilizer consists of:-
Nitrogen 19%
Phosphate (P2O5) 19%
Potash (K2O) 19%
Magnesium (MgO) 1%
Sulphur (S) 3%
Iron (EDTA) 0.1%
Maganese (EDTA) 0.05%
Copper (EDTA) 0.01%
Zinc (EDTA) 0.05%
Boron 0.02%
Molubdenum 0.001%
It is acidic due to raw material used in their manufacture like Phosphoric Acid, Nitric Acid,, Sulphuric Acid and Sulphate of Micronutrients. When dissolved in water, nutrients become their Ions like NO3, K+, P+ etc. and become chemically active. One single fertilizer contains all nutrients (except Calcium) in balanced ratio, thus providing full nourishment for healthy growth and high yield. For using these fertilizer via drip, mini sprinlder or foliar spray system, a dilute water solution is prepared and this solution is applied to root zone, plants and their leaves.
The residual solution in root zone reacts with calcareous or alkaline soil elements and reduces the pH of the soil towards neutral over the period of time. Thus using water soluble complex acidic fertilizers through drip, mini sprinkler or foliar spray systems, over a long period of cultivation, shall improve the nature of soil toward suitable pH and higher fertility.

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